References
For the overall reaction:
Renata, H.; Zhou, Q.; Baran, P. S. Science 2013, 339, 59-63.
Barton, O’Brien, and Sternhell use this article and the protocol described within it in order to demonstrate how they converted the ketone portion (16) of a larger molecule into a vinyl iodide (intermediate between 16 and 18). The article explains how Barton, O’Brien, and Sternhell unintentionally came across, but developed and proved a method to convert ketones and aldehydesinto hydrazones. Then, through oxidation by iodide, vinyl iodides or gem-ni-iodides are formed.
Barton's Protocol:
Barton, D. H. R.; O'Brien, R. E.; Sternhell, S. J. Chem. Soc. 1962, 470-476.
References citing Barton's Protocol reaction:
Barton, D. H. R.; Bashiardes, G.; Fourrey, J.-L. Tetrahedron Lett. 1983, 24, 1605-1608.
Farkas, R.; Molnár, E. A.; Ács, P.; Takács, A. Tetrahedron 2013, 69, 500-504.
Shi, J.; Manolikakes, G.; Yeh, C.-H.; Guerrero, C. A.; Shenvi, R. A.; Shigehisa, H.; Baran, P. S. J. Am. Chem. Soc. 2011, 133, 8014-8027.
